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Sigma-Aldrich Quality Level 200 assay 98% form solid reaction suitability core: palladium reaction
List Price
$966.00
Your Price
$966.00
Sigma-Aldrich Quality Level 200 assay 98% form solid reaction suitability core: palladium reaction type: Cross Couplings reagent type: catalyst reaction type: C-H Activation greener alternative - SIALUPENN (Additional S&H or Hazmat Fees may Apply)
NETA PART:
SIALUPENN-222380-10G
MFG.PART:
222380-10G
UNSPSC:
41122409
Manufacturer:
Sigma-Aldrich
Quality Level
200
assay
98%
form
solid
reaction suitability
core: palladium
reaction type: Cross Couplings
reagent type: catalyst
reaction type: C-H Activation
greener alternative product characteristics
Catalysis
Learn more about the Principles of Green Chemistry.
sustainability
Greener Alternative Product
greener alternative category
, Aligned
storage temp.
2-8°C
SMILES string
Cl[Pd]CC=C.Cl[Pd]CC=C
InChI
1S/2C3H5.2ClH.2Pd/c2*1-3-2;;;;/h2*3H,1-2H2;2*1H;;/q;;;;2*+1/p-2
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Related Categories
Catalysts
Chemistry & Biochemicals
Cross-Coupling Catalysts
C–H Activation Catalysts
Greener Alternative Products
General description
Allylpalladium(II) chloride dimer is employed as catalyst in Heck reaction. It also participates as catalyst in the tandem nucleophilic allylation-alkoxyallylation reaction of the alkynylaldehydes with allyl chloride and allyltributylstannane.[1]
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application
Application Guide for Palladium Catalyzed Cross-Coupling Reactions
Allylpalladium(II) chloride dimer has been employed for the following studies:
On the Way Towards Greener Transition-Metal-Catalyzed Processes as Quantified by E Factors
- Synthesis of cationic palladium cataysts, used in the microwave-assisted Heck arylation.[2]
- Synthesis of N-heterocyclic carbene-palladium-η3-allyl chloride complexes, which are efficient catalyst for the Suzuki-Miyaura cross-coupling of aryl bromides and activated aryl chlorides.[3]
- Synthesis of 1,4-diallyl-1,2-dihydroisoquinolines.[4]
- As catalyst for greener Buchwald-Hartwig coupling in TPGS-750-M.
On the Way Towards Greener Transition-Metal-Catalyzed Processes as Quantified by E Factors
pictograms
GHS07
signalword
Warning
hcodes
H315
pcodes
P264 - P280 - P302 + P352 - P332 + P313 - P362 + P364
Hazard Classifications
Skin Irrit. 2
Storage Class
11 - Combustible Solids
wgk_germany
WGK 3
ppe
dust mask type N95 (US), Eyeshields, Faceshields, Gloves
| SKU | SIALUPENN-222380-10G |
|---|---|
| Supplier Part Number | 222380-10G |
| UM | EA |
| UNSPSC | 41122409 |
| Manufacturer | Sigma-Aldrich |
| ProductLine | SIALUPENN |
| Qty | 1 |
| MinOrderQty | 1 |
| Weight | 7.000000 |
| Lead Time | 9 |
| Hazardous | N |
| Energy Star | No |
| Green | No |
| Controlled | N |