Sigma-Aldrich Quality Level 100 form solid reaction suitability core: ruthenium reagent type: cataly

Name: Sigma-Aldrich Quality Level 100 form solid reaction suitability core: ruthenium reagent type: cataly
SKU: SIALUPENN-569747-25G
Price: 1510.00 USD

List Price $1,510.00 Your Price $1,510.00

Sigma-Aldrich Quality Level 100 form solid reaction suitability core: ruthenium reagent type: catalyst reaction type: Ring-Opening Polymerization mp 143.5-148.5 °C storage temp. 2-8°C SMILES string - SIALUPENN (Additional S&H or Hazmat Fees may Apply)

NETA PART: SIALUPENN-569747-25G

MFG.PART: 569747-25G

UNSPSC: 41122409

Manufacturer: Sigma-Aldrich

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Description

Quality Level

100

form

solid

reaction suitability

core: ruthenium
reagent type: catalyst
reaction type: Ring-Opening Polymerization

mp

143.5-148.5 °C

storage temp.

2-8°C

SMILES string

CC1=CC(C)=CC(C)=C1N2CCN(C3=C(C)C=C(C)C=C3C)C2=[Ru](Cl)(Cl)=CC4=CC=CC=C4.P(C5CCCCC5)(C6CCCCC6)C7CCCCC7

InChI

1S/C21H26N2.C18H33P.C7H6.2ClH.Ru/c1-14-9-16(3)20(17(4)10-14)22-7-8-23(13-22)21-18(5)11-15(2)12-19(21)6;1-4-10-16(11-5-1)19(17-12-6-2-7-13-17)18-14-8-3-9-15-18;1-7-5-3-2-4-6-7;;;/h9-12H,7-8H2,1-6H3;16-18H,1-15H2;1-6H;2*1H;/q;;;;;+2/p-2

InChI key

FCDPQMAOJARMTG-UHFFFAOYSA-L

Application

Grubbs Catalyst^® M204 can be used as a catalyst for ring-closing metathesis (RCM), cross-metathesis, and ring-opening metathesis polymerization (ROMP).[1][2][3] It is also used to synthesize trisubstituted olefins with excellent functional group tolerance and selectivity via cross-metathesis and ring closing metathesis reactions.[4][5]
It can also be used as a catalyst:

To synthesize coumarins from phenolic compounds via RCM.[1]
To cleave secondary (E)-allyl vic-diols to aldehydes.[6]

For small scale and high throughput uses, product is also available as ChemBeads (919764)

Learn more about our metathesis catalysts

Other Notes

Grubbs Catalyst® Technology for Olefin Metathesis by Aldrich

569755 Hoveyda-Grubbs Catalyst® 2nd Generation

Legal Information

Product of Umicore

Product License
This product, its manufacturing or use, is the subject of one or more issued or pending U.S. Patents (and foreign equivalents) owned or controlled by Umicore PMC. The purchase of this product from Umicore PMC through Sigma-Aldrich, its affiliates or their authorized distributors conveys to the buyer a limited, one-time, non-exclusive, non-transferable, non-assignable license. Buyer′s use of this product may infringe patents owned or controlled by third parties. It is the sole responsibility of buyer to ensure that its use of the product does not infringe the patent rights of third parties or exceed the scope of the license granted herein.

For any further information on product please refer to your local Umicore PMC contact at http://www.pmc.umicore.com

Grubbs Catalyst is a registered trademark of Umicore AG & Co. KG

pictograms

GHS02

signalword

Warning

hcodes

H228

pcodes

P210 - P240 - P241 - P280 - P370 + P378

Hazard Classifications

Flam. Sol. 2

Storage Class

4.1B - Flammable solid hazardous materials

wgk_germany

WGK 3

flash_point_f

Not applicable

flash_point_c