Sigma-Aldrich Quality Level 100 assay ≥98.0% (T) form crystals mp 98-100 °C (lit.) SMILES string

Name: Sigma-Aldrich Quality Level 100 assay ≥98.0% (T) form crystals mp 98-100 °C (lit.) SMILES string
SKU: SIALUPENN-87303-100G
Price: 1180.00 USD

List Price $1,180.00 Your Price $1,180.00

Sigma-Aldrich Quality Level 100 assay ≥98.0% (T) form crystals mp 98-100 °C (lit.) SMILES string OS([O-])(=O)=O.CCCCCC[N+](CCCCCC)(CCCCCC)CCCCCC InChI - SIALUPENN (Additional S&H or Hazmat Fees may Apply)

NETA PART: SIALUPENN-87303-100G

MFG.PART: 87303-100G

UNSPSC: 41122409

Manufacturer: Sigma-Aldrich

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Description

Quality Level

100

assay

≥98.0% (T)

form

crystals

mp

98-100 °C (lit.)

SMILES string

OS([O-])(=O)=O.CCCCCC[N+](CCCCCC)(CCCCCC)CCCCCC

InChI

1S/C24H52N.H2O4S/c1-5-9-13-17-21-25(22-18-14-10-6-2,23-19-15-11-7-3)24-20-16-12-8-4;1-5(2,3)4/h5-24H2,1-4H3;(H2,1,2,3,4)/q+1;/p-1

InChI key

RULHPTADXJPDSN-UHFFFAOYSA-M

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Application

Tetrahexylammonium hydrogensulfate can be used as a phase-transfer agent to facilitate certain organic reactions in a two-liquid phase system. For example:

Epoxidation of α,β-unsaturated ketones in a biphasic dichloromethane/water mixture using sodium perborate.[1]
Transfer hydrogenolysis of aryl bromides by aqueous sodium formate catalyzed by palladium-triphenylphospine.[2]
Carbonylation of benzylic and allylic bromides to synthesize carboxylic esters.[3]

Other Notes

Lipophilic phase transfer catalyst. Most efficient catalyst in ruthenium-catalyzed reactions[4]

pictograms

GHS07

signalword

Warning

hcodes

H315,H319,H335

pcodes

P261 - P264 - P271 - P280 - P302 + P352 - P305 + P351 + P338

Hazard Classifications

Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3

target_organs

Respiratory system

Storage Class

11 - Combustible Solids

wgk_germany

WGK 3

flash_point_f

Not applicable

flash_point_c