Sigma-Aldrich (R)-1-{(RP)-2-[2-(DIPHENYLPHOSPHINO)PHE

Name: Sigma-Aldrich (R)-1-{(RP)-2-[2-(DIPHENYLPHOSPHINO)PHE
SKU: SIALMSD-65671-100MG
Price: 105.27 USD

List Price $105.27 Your Price $105.27

Sigma-Aldrich The product is an air-stable and non-hygroscopic Solvias chiral phosphine ligand. - SIALMSD (Additional S&H or Hazmat Fees May Apply)

NETA PART: SIALMSD-65671-100MG

MFG.PART: 65671-100MG

UNSPSC: 12350000

Manufacturer: Sigma-Aldrich

Quality Level
100

assay
≥97%

optical purity
ee: ≥99%

functional group
fluoro phosphine

SMILES string
[Fe].[CH]1[CH][CH][CH][CH]1.C[C@@H]([C]2[CH][CH][CH][C]2c3ccccc3P(c4ccccc4)c5ccccc5)P(c6cc(cc(c6)C(F)(F)F)C(F)(F)F)c7cc(cc(c7)C(F)(F)F)C(F)(F)F

InChI
1S/C41H27F12P2.C5H5.Fe/c1-25(34-16-10-17-35(34)36-15-8-9-18-37(36)55(30-11-4-2-5-12-30)31-13-6-3-7-14-31)54(32-21-26(38(42,43)44)19-27(22-32)39(45,46)47)33-23-28(40(48,49)50)20-29(24-33)41(51,52)53;1-2-4-5-3-1;/h2-25H,1H3;1-5H;/t25-;;/m0../s1

InChI key
LKNKYBWIZNAXBY-WLOLSGMKSA-N

General description
Application Walphos SL-W001-2, in the presence of a ruthenium catalyst may be used as a ligand in the following processes: Asymmetric hydrogenation of IPCA-D, a cinnamic acid derivative.[1] Addition of 3,5-difluorophenylketimine to 4-methoxyphenylboronic acid to form the corresponding tertiary substituted cyclic sulfamate derivative with high enantioselctivity.2[2]

Packaging
Other Notes sold in collaboration with Solvias AG