Sigma-Aldrich (R)-1-[(SP)-2-(DICYCLOHEXYLPHOSPHINO)FE

Name: Sigma-Aldrich (R)-1-[(SP)-2-(DICYCLOHEXYLPHOSPHINO)FE
SKU: SIALMSD-88723-100MG
Price: 109.78 USD

List Price $109.78 Your Price $109.78

Sigma-Aldrich (R)-1-[(SP)-2-(DICYCLOHEXYLPHOSPHINO)FE - SIALMSD (Additional S&H or Hazmat Fees May Apply)

NETA PART: SIALMSD-88723-100MG

MFG.PART: 88723-100MG

UNSPSC: 12350000

Manufacturer: Sigma-Aldrich

Quality Level
100

assay
≥97%

form
crystals

optical purity
ee: ≥99%

functional group
phosphine

SMILES string
[Fe].[CH]1[CH][CH][CH][CH]1.C[C@H]([C]2[CH][CH][CH][C]2P(C3CCCCC3)C4CCCCC4)P(c5ccccc5)c6ccccc6

InChI
1S/C31H39P2.C5H5.Fe/c1-25(32(26-15-6-2-7-16-26)27-17-8-3-9-18-27)30-23-14-24-31(30)33(28-19-10-4-11-20-28)29-21-12-5-13-22-29;1-2-4-5-3-1;/h2-3,6-9,14-18,23-25,28-29H,4-5,10-13,19-22H2,1H3;1-5H;/t25-;;/m1../s1

InChI key
AWOOIDCKLIQAJV-KHZPMNTOSA-N

General description
Application (R)-1-[(S_P)-2-(Dicyclohexylphosphino)ferrocenylethyl]diphenylphosphine can be used as a ligand: To prepare iridium metal complex (Ir^IJOSIPHOS), which is used as a catalyst in the asymmetric hydrogenation of 2-phenylquinoxaline.[1] In the preparation of natural products by asymmetric conjugate addition of Grignard reagents to α-substituted cyclic alkenones.[2]