Sigma-Aldrich Ssphos Pd G2

Name: Sigma-Aldrich Ssphos Pd G2
SKU: SIAL-763314-5G
Price: 1459.50 USD

List Price $1,459.50 Your Price $1,459.50

Sigma-Aldrich Ssphos Pd G2 - SIAL (Additional S&H or Hazmat Fees May Apply)

NETA PART: SIAL-763314-5G

MFG.PART: 763314-5G

UNSPSC: 12352128

Manufacturer: Sigma-Aldrich

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Description

Product Name

sSPhos Pd G2, 95%

Quality Level

100

assay

95%

form

solid

feature

generation 2

reaction suitability

core: palladium
reaction type: Buchwald-Hartwig Cross Coupling Reaction
reaction type: Heck Reaction
reaction type: Hiyama Coupling
reaction type: Negishi Coupling
reaction type: Sonogashira Coupling
reaction type: Stille Coupling
reaction type: Suzuki-Miyaura Coupling
reagent type: catalyst
reaction type: Cross Couplings

mp

193-194 °C (decomposition)

functional group

phosphine

SMILES string

[Na+].Nc1ccccc1-c2ccccc2[Pd]Cl.COc3ccc(c(OC)c3-c4ccccc4P(C5CCCCC5)C6CCCCC6)S([O-])(=O)=O

InChI

1S/C26H35O5PS.C12H10N.ClH.Na.Pd/c1-30-22-17-18-24(33(27,28)29)26(31-2)25(22)21-15-9-10-16-23(21)32(19-11-5-3-6-12-19)20-13-7-4-8-14-20;13-12-9-5-4-8-11(12)10-6-2-1-3-7-10;;;/h9-10,15-20H,3-8,11-14H2,1-2H3,(H,27,28,29);1-6,8-9H,13H2;1H;;/q;;;2*+1/p-2

Related Categories

Buchwald Catalysts & Ligands

Catalysts

Cross-Coupling Catalysts

Palladium Catalysts

Transition Metal Catalysts

Application

sSPhos Pd G2 can be used as a water-soluble Pd-precatalyst in:

DNA-compatible Suzuki-Miyaura reaction between DNA-linked aryl halides and various boronic acids/esters including heteroaryl boronates[1].
DNA-compatible hydroxycarbonylation reactions[2].
The cross-coupling reaction between boronic ester and brominated cyclic nucleotide to synthesize cyclic adenosine and guanosine monophosphate in the presence of potassium phosphate and hydrochloric acid[3].

Storage Class

11 - Combustible Solids

wgk_germany

WGK 3

flash_point_f

Not applicable

flash_point_c