Sigma-Aldrich Mordalphos Pd G4

Name: Sigma-Aldrich Mordalphos Pd G4
SKU: SIAL-900455-5G
Price: 2383.50 USD

List Price $2,383.50 Your Price $2,383.50

Sigma-Aldrich Mordalphos Pd G4; 5 g - SIAL (Additional S&H or Hazmat Fees May Apply)

NETA PART: SIAL-900455-5G

MFG.PART: 900455-5G

UNSPSC: 12352100

Manufacturer: Sigma-Aldrich

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Description

Product Name

N-XantPhos Pd G4,

form

powder or crystals

Quality Level

100

feature

generation 4

reaction suitability

reaction type: Buchwald-Hartwig Cross Coupling Reaction
reaction type: Heck Reaction
reaction type: Hiyama Coupling
reaction type: Negishi Coupling
reaction type: Sonogashira Coupling
reaction type: Stille Coupling
reaction type: Suzuki-Miyaura Coupling
reagent type: catalyst
reaction type: Cross Couplings

functional group

phosphine

SMILES string

[Pd+]c8c(cccc8)c9c(cccc9)NC.P(c7ccccc7)(c6ccccc6)c1c2c(ccc1)Nc3c(c(ccc3)P(c5ccccc5)c4ccccc4)O2.[S](=O)(=O)([O-])C

InChI

1S/C36H27NOP2.C13H12N.CH4O3S.Pd/c1-5-15-27(16-6-1)39(28-17-7-2-8-18-28)33-25-13-23-31-35(33)38-36-32(37-31)24-14-26-34(36)40(29-19-9-3-10-20-29)30-21-11-4-12-22-30;1-14-13-10-6-5-9-12(13)11-7-3-2-4-8-11;1-5(2,3)4;/h1-26,37H;2-7,9-10,14H,1H3;1H3,(H,2,3,4);

Inchi Key

XLDCAOXDZXRMKY-UHFFFAOYSA-M

Application

N-XantPhos Pd G4 is a fourth generation (G4) Buchwald precatalyst that is similar to the third generation (G3) precatalysts except that the amino group on the biphenyl backbone is methylated. This modification helps to prevent the limitations found when using the third generation precatalysts. It is air, moisture, and thermally-stable and shows good solubility in common organic solvents.

Storage Class

11 - Combustible Solids

wgk_germany

WGK 3

flash_point_f

Not applicable

flash_point_c