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Sigma-Aldrich Dichlorophenylborane 97%
List Price
$57.65
Your Price
$57.65
Sigma-Aldrich Dichlorophenylborane 97% - SIAL (Additional S&H Or Hazmat Fees May Apply)
NETA PART:
SIAL-101346-1G
MFG.PART:
101346-1G
UNSPSC:
12352000
Manufacturer:
Sigma-Aldrich
Quality Level
100
assay
97%
reaction suitability
reagent type: reductant
refractive index
n20/D 1.545 (lit.)
bp
66 °C/11 mmHg (lit.)
density
1.224 g/mL at 25 °C (lit.)
SMILES string
ClB(Cl)c1ccccc1
InChI
1S/C6H5BCl2/c8-7(9)6-4-2-1-3-5-6/h1-5H
InChI key
NCQDQONETMHUMY-UHFFFAOYSA-N
Related Categories
Reducing Agents
Application
Catalyst for:
- Antiproliferative macrolide and cell migration inhibitor lactimidomycin
- Enantioselective synthesis of polyketide segments using vinylogous Mukaiyama aldol reactions
- Enantioselective Diels-Alder cycloadditions after its reaction with allo-threonine derivatives
- Stereoselective alkylative ring opening of cyclic anhydrides
- Cross-metathesis reaction of amino derivatives with olefins
- Asymmetric acetate aldol reactions
- The reaction of aryl aldehydes with styrene and (E)-β-methylstyrene
Dichlorophenylborane can be used as a catalyst for:
- The synthesis of an antiproliferative macrolide and cell migration inhibitor lactimidomycin.[1]
- Enantioselective synthesis of polyketide segments using vinylogous Mukaiyama aldol reactions.[2]
- Enantioselective Diels-Alder cycloadditions after its reaction with allo-threonine derivatives.[3]
- Stereoselective alkylative ring opening of cyclic anhydrides.[4]
- Cross-metathesis reaction of amino derivatives with olefins.[5]
- Asymmetric acetate aldol reactions.[6]
pictograms
GHS02,GHS05
signalword
Danger
hcodes
H225,H314
pcodes
P210 - P233 - P240 - P280 - P303 + P361 + P353 - P305 + P351 + P338
Hazard Classifications
Flam. Liq. 2 - Skin Corr. 1B
wgk_germany
WGK 3
ppe
Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter
| SKU | SIAL-101346-1G |
|---|---|
| Featured | No |
| Supplier Part Number | 101346-1G |
| UM | EA |
| UNSPSC | 12352000 |
| Manufacturer | Sigma-Aldrich |
| Temperature | room temp |
| Refrigerated-Frozen | N |
| ProductLine | SIAL |
| Qty | 1 |
| MinOrderQty | 1 |
| Weight | 10.000000 |
| Lead Time | 9 |
| Hazardous | Y |
| CAS Number | 873-51-8 |
| Energy Star | No |
| Green | No |
| ACT Ecolabel | No |
| Controlled | N |