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Sigma-Aldrich Di-tert-butyl azodicarboxylate
List Price
$49.46
Your Price
$49.46
Sigma-Aldrich Di-Tert-Butyl Azodicarboxylate - SIAL (Additional S&H Or Hazmat Fees May Apply)
NETA PART:
SIAL-11625-5G-F
MFG.PART:
11625-5G-F
UNSPSC:
12352000
Manufacturer:
Sigma-Aldrich
grade
purum
Quality Level
200
assay
≥98.0% (GC)
form
solid
mp
89-92 °C (lit.)
89-92 °C
storage temp.
2-8°C
SMILES string
CC(C)(C)OC(=O)\N=N\C(=O)OC(C)(C)C
InChI
1S/C10H18N2O4/c1-9(2,3)15-7(13)11-12-8(14)16-10(4,5)6/h1-6H3/b12-11+
InChI key
QKSQWQOAUQFORH-VAWYXSNFSA-N
Related Categories
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General description
Di-tert-butyl azodicarboxylate is a an acid labile reagent for Mitsunobu reactions allowing facile isolation of products[1] and for the electrophilic amination and hydrazination of enolates and lithium alkyls.[2][3][4]
Application
Reactant for:
- Preparation of hexapeptide key fragments via stereoselective selenocyclization/oxidative deselenylation or hydrazination/cyclization reactions
- Asymmetric Michael addition reactions
- Preparation of dipeptidyl peptidase IV dependent water-soluble prodrugs via Mitsunobu reaction
- Synthesis of pyrroloisoquinoline template via stereoselective N-acyliminium-mediated cyclization and enolate amination for synthesis of peptidomimetic compounds
- Barbier-type propargylation reactions
- Synthesis of bacterial peptide deformylase (PDF) inhibitor fumimycin
- Asymmetric amination of glycine Schiff bases
wgk_germany
WGK 3
ppe
dust mask type N95 (US), Eyeshields, Gloves
| SKU | SIAL-11625-5G-F |
|---|---|
| Featured | No |
| Supplier Part Number | 11625-5G-F |
| UM | EA |
| UNSPSC | 12352000 |
| Manufacturer | Sigma-Aldrich |
| Temperature | 2-8C |
| Refrigerated-Frozen | Y |
| ProductLine | SIAL |
| Qty | 1 |
| MinOrderQty | 1 |
| Weight | 10.000000 |
| Lead Time | 9 |
| Hazardous | Y |
| CAS Number | 870-50-8 |
| Energy Star | No |
| Green | No |
| ACT Ecolabel | No |
| Controlled | N |