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Sigma-Aldrich Methyl Thioglycolate 95%
List Price $42.00 Your Price $42.00
Sigma-Aldrich Methyl Thioglycolate 95% - SIAL (Additional S&H Or Hazmat Fees May Apply)
NETA PART: SIAL-108995-5G
MFG.PART: 108995-5G
UNSPSC: 12352100
Manufacturer: Sigma-Aldrich
Quality Level
200
assay
95%
reaction suitability
reagent type: ligand
reaction type: [1,2]-Wittig Rearrangement
refractive index
n20/D 1.466 (lit.)
bp
42-43 °C/10 mmHg (lit.)
density
1.187 g/mL at 25 °C (lit.)
SMILES string
COC(=O)CS
InChI
1S/C3H6O2S/c1-5-3(4)2-6/h6H,2H2,1H3
InChI key
MKIJJIMOAABWGF-UHFFFAOYSA-N
Related Categories
Organic Building Blocks
Thiols
General description
Methyl thioglycolate reacts with nonprotein component of the antitumor antibiotic neocarzinostatin to form 1:1 adduct[1]. It reacts with isothiocyanate to form Rhodanine[2].
Application
Methyl thioglycolate was used in the preparation of:
A General Strategy for Organocatalytic Activation of C–H Bonds via Photoredox Catalysis: Direct Arylation of Benzylic Ethers
Product can be used with our line of photoreactors: Including Penn PhD (Z744035) & SynLED 2.0 (Z744080)
- 3-carbomethoxy-4- oxotetrahydrothiopyran, 2- and 4-carbomethoxy-3-oxotetrahydrothiophene[3]
- methyl thioglycolate and aminoethanethiol conjugated gold nanorods[4].
A General Strategy for Organocatalytic Activation of C–H Bonds via Photoredox Catalysis: Direct Arylation of Benzylic Ethers
Product can be used with our line of photoreactors: Including Penn PhD (Z744035) & SynLED 2.0 (Z744080)
pictograms
GHS02,GHS06
signalword
Danger
hcodes
H226,H301,H315,H319,H332,H335
pcodes
P210 - P233 - P301 + P310 - P303 + P361 + P353 - P304 + P340 + P312 - P305 + P351 + P338
Hazard Classifications
Acute Tox. 3 Oral - Acute Tox. 4 Inhalation - Eye Irrit. 2 - Flam. Liq. 3 - Skin Irrit. 2 - STOT SE 3
target_organs
Respiratory system
wgk_germany
WGK 1
PPE
Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter
| SKU | SIAL-108995-5G |
|---|---|
| Supplier Part Number | 108995-5G |
| UM | EA |
| UNSPSC | 12352100 |
| Manufacturer | Sigma-Aldrich |
| Temperature | room temp |
| Refrigerated-Frozen | N |
| ProductLine | SIAL |
| Qty | 1 |
| MinOrderQty | 1 |
| Weight | 10.000000 |
| Lead Time | 9 |
| Hazardous | Y |
| CAS Number | 2365-48-2 |
| Energy Star | No |
| Green | No |
| Controlled | N |