Sigma-Aldrich Methyl Thioglycolate 95%

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Sigma-Aldrich Methyl Thioglycolate 95% - SIAL (Additional S&H Or Hazmat Fees May Apply)
NETA PART: SIAL-108995-5G
MFG.PART: 108995-5G
UNSPSC: 12352100
Manufacturer: Sigma-Aldrich

Quality Level

200

assay

95%

reaction suitability

reagent type: ligand
reaction type: [1,2]-Wittig Rearrangement

refractive index

n20/D 1.466 (lit.)

bp

42-43 °C/10 mmHg (lit.)

density

1.187 g/mL at 25 °C (lit.)

SMILES string

COC(=O)CS

InChI

1S/C3H6O2S/c1-5-3(4)2-6/h6H,2H2,1H3

InChI key

MKIJJIMOAABWGF-UHFFFAOYSA-N

Related Categories

Organic Building Blocks

Thiols

General description

Methyl thioglycolate reacts with nonprotein component of the antitumor antibiotic neocarzinostatin to form 1:1 adduct[1]. It reacts with isothiocyanate to form Rhodanine[2].

Application

Methyl thioglycolate was used in the preparation of:
  • 3-carbomethoxy-4- oxotetrahydrothiopyran, 2- and 4-carbomethoxy-3-oxotetrahydrothiophene[3]
  • methyl thioglycolate and aminoethanethiol conjugated gold nanorods[4].
Thiol Organocatalyst used in conjunction with visible light photocatalysis to affect the direct arylation of benzylic ether C-H bonds

A General Strategy for Organocatalytic Activation of C–H Bonds via Photoredox Catalysis: Direct Arylation of Benzylic Ethers

Product can be used with our line of photoreactors: Including Penn PhD (Z744035) & SynLED 2.0 (Z744080)

pictograms

GHS02,GHS06

signalword

Danger

hcodes

H226,H301,H315,H319,H332,H335

pcodes

P210 - P233 - P301 + P310 - P303 + P361 + P353 - P304 + P340 + P312 - P305 + P351 + P338

Hazard Classifications

Acute Tox. 3 Oral - Acute Tox. 4 Inhalation - Eye Irrit. 2 - Flam. Liq. 3 - Skin Irrit. 2 - STOT SE 3

target_organs

Respiratory system

wgk_germany

WGK 1

ppe

Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter

More Information
SKU SIAL-108995-5G
Featured No
Supplier Part Number 108995-5G
UM EA
UNSPSC 12352100
Manufacturer Sigma-Aldrich
Temperature room temp
Refrigerated-Frozen N
ProductLine SIAL
Qty 1
MinOrderQty 1
Weight 10.000000
Lead Time 9
Hazardous Y
CAS Number 2365-48-2
Energy Star No
Green No
ACT Ecolabel No
Controlled N
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